Diamonds Are Not Just for Jewelry Anymore

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Diamond Photoconductive Switch

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A photoconductive switch made from an artificial, chemical vapor deposition diamond under test. Credit: LLNL

When it pertains to the semiconductor market, silicon has actually ruled as king in the electronic devices field, however it is coming to the end of its physical limitations.

To better power the electrical grid, engines, and even electrical automobiles, Lawrence Livermore National Laboratory (LLNL) researchers are relying on diamond as an ultra-wide bandgap semiconductor.

Diamond has actually been revealed to have remarkable provider movement, break down electrical field and thermal conductivity, the most crucial residential or commercial properties to power electronic gadgets. It ended up being specifically preferable after the advancement of a chemical vapor deposition (CVD) procedure for development of premium single crystals.

The group checked out residential or commercial properties of such artificially made diamonds that are greater quality than naturally happening ones. “In electronics you want to start from as pure material as you can so you can mold it into a device with desired properties,” stated LLNL physicist Paulius Grivickas, lead author of a paper appearing in Applied Physics Letters.

In photoconductive gadgets, the very best mix of conductivity and frequency action is accomplished by presenting pollutants, which manage provider recombination life times. Researchers discovered that in diamond, an inexpensive and simple option to this method is electron irradiation where recombination problems are developed by knocking the lattice atoms out of location.

“We said to ourselves ‘let’s take this pure high quality CVD diamond and irradiate it to see if we can tailor the carrier lifetime,’” Grivackas stated. “Eventually, we nailed down the understanding of which irradiation defect is responsible for carrier lifetimes and how does the defect behave under annealing at technologically relevant temperatures.”

Photoconductive diamond changes produced in this manner can be utilized, for instance, in the power grid to manage existing and voltage rises, which can fry out the devices. Current silicon switches are huge and large, however the diamond-based ones can achieve the exact same thing with a gadget that might fit on the suggestion of a finger, Grivickas stated.

The research study likewise has applications in the energy shipment systems where the group showed a possibility of a megawatt-class radio frequency power generation, which needs optimization of diamond’s high-frequency action.

Livermore engineers Lars Voss and Adam Conway in addition to scientists from Vilnius University in Lithuania, Belarusian State University and the National Academy of Sciences in Belarus worked together in this work.

Reference: “Carrier recombination and diffusion in high-purity diamond after electron irradiation and annealing” by P. Grivickas, P. Ščajev, N. Kazuchits, S. Lastovskii, L. F. Voss, A. M. Conway, A. Mazanik, O. Korolik, V. Bikbajevas and V. Grivickas, 14 December 2020, Applied Physics Letters.
DOI: 10.1063/5.0028363

The research study was moneyed by LLNL’s Laboratory Directed Research and Development program.